Beschreibung
Written for chemists in industry and academia, this ready reference and handbook summarizes recent progress in the development of new catalysts that do not require precious metals. The research thus presented points the way to how new catalysts may ultimately supplant the use of precious metals in some types of reactions, while highlighting the remaining challenges. An essential copanion for organic and catalytic chemists, as well as those working with/on organometallics and graduate students. From the contents: * Catalysis Involving the H' Transfer Reactions of First-Row Transition Metals * Catalytic Reduction of Dinitrogen to Ammonia by Molybdenum Complexes * Molybdenum and Tungsten Catalysts for Hydrogenation, Hydrosilylation and Hydrolysis * Iron in Catalytic Alkene and Carbonyl Hydrogenation Reactions * Olefin Oligomerizations and Polymerizations Catalyzed by Iron and Cobalt Complexes * Cobalt and Nickel Catalyzed Reactions Involving C-H and C-N Activation Reactions * Development of Molecular Electrocatalysts for H2 Oxidation and Production Based on Inexpensive Metals * NickelCatalyzed Reductinve Couplings and Cyclizations * CopperCatalyzed Ligand Promoted UllmannType Coupling Reactions * CopperCatalyzed AzideAlkyne Cycloaddition * "Frustrated Lewis Pairs": A Metal-Free Strategy for Hydrogenation Catalysis
Autorenportrait
InhaltsangabePreface CATALYSIS INVOLVING THE H*TRANSFER REACTIONS OF FIRST-ROW TRANSITION METALS H*Transfer Between M-H Bonds and Organic Radicals H*Transfer Between Ligands and Organic Radicals H*Transfer Between M-H and C-C Bonds Chain Transfer Catalysis Catalysis of Radical Cyclizations Competing Methods for the Cyclization of Dienes Summary and Conclusions CATALYYTIC REDUCTION OF DINITROGEN TO AMMONIA BY MOLYBDENUM Introduction Some Characteristics of Triamidoamine Complexes Possible [HIPTN3N]Mo Intermediates in a Catalytic Reduction of Molecular Nitrogen Interconversion of Mo(NH3) and Mo(N2) Catalytic Reduction of Dinitrogen MoH and Mo(H2) Ligand and Metal Variations Comments MOLYBDENUM AND TUNGSTEN CATALYSTS FOR HYDROGENATION, HYDROSILYLATION AND HYDROLYSIS Introduction Proton Transfer Reactions of Metal Hydrides Hydride Transfer Reactdions of Metal Hydrides Stoichiometric Hydride Transfer Reactivity of Anionic Metal Hydride Complexes Catalytic Hydrogenation of Ketones with Anionic Metal Hydrides Ionic Hydrogenation of Ketones Using Metal Hydrides and Added Acid Ionic Hydrogenations from Dihydrides: Delivery of the Proton and Hydride from One Metal Catalytic Ionic Hydrogenations With Mo and W Catalysts Mo Phosphine Catalysts With Improved Lifetimes Tungsten Hydrogenation Catalysts with N-Heterocyclic Carbene Ligands Catalysts for Hydrosilylation of Ketones Cp2Mo Catalysts for Hydrolysis, Hydrogenations and Hydrations Conclusion MODERN ALCHEMY: REPLACING PRECIOUS METALS WITH IRON IN CATALYTIC ALKENE AND CARBONYL HYDROGENATION REACTIONS Introduction Alkene Hydrogenation Carbonyl Hydrogenation Outlook OLEFIN OOLIGOMERIZATIONS AND POLYMERIZATIONS CATALYZED BY IRON AND COBALT COMPLEXES BEARING BIS(IMINO)PYRIDINE LIGANDS Introduction Precatalyst Synthesis Precatalyst Activation and Catalysis The Active Catalyst and Mechanism Other Applications Conclusions and Outlook COBALT AND NICKEL CATALYZED REACTIONS INVOLVING C-H AND C-N ACTIVATION REACTIONS Introduction Catalysis with Cobalt Catalysis with Nickel A MODULAR APPROACH TO THE DEVELOPMENT OF MOLECULAR ELECTROCATALYSTS FOR H2 OXIDATION AND PRODUCTION BASED ON INEXPENSIVE METALS Introduction Concepts in Catalyst Design Based on Structural Studies of Hydrogenase Enzymes A Layered or Modular Approach to Catalyst Design Using the First Coordination Sphere to Control the Energies of Catalytic Intermediates Using the Second Coordination Sphere to Control the Movement of Protons between the Metal and the Exterior of the Molecular Catalyst Integration of the First and Second Coordination Spheres Summary NICKELCATALYZED REDUCTIVE COUPLINGS AND CYCLIZATIONS Introduction Couplings of Alkynes with alpha, beta-Unsaturated Carbonyls Couplings of Alkynes with Aldehydes Conclusions and Outlook COPPERCATALYZED LIGAND PROMOTED ULLMANNTYPE COUPLING REACTIONS Introduction CN Bond Formation CO Bond Formation CC Bond Formation CS Bond Formation CP Bond Formation Conclusion COPPERCATALYZED LIGAND PROMOTED ULLMANNTYPE COUPLING REACTIONS Introduction CN Bond Formation CO Bond Formation CC Bond Formation CS Bond Formation CP Bond Formation Conclusion COPPERCATALYZED AZIDEALKYNE CYCLOADDITION (CuAAC) Introduction AzideAlkyne Cycloaddition: Basics CopperCatalyzed Cycloadditions "FRUSTRATED LEWIS PAIRS": A METAL-FREE STRATEGY FOR HYDROGENATION CATALYSIS PhosphineBorane Activation of H2 "Frustrated Lewis Pairs" MetalFree Catalytic Hydrogenation Future Considerations
